Optimization of solubilization capacity of RM is a much anticipated field of research in surface science as high water uptake of RMs is often beneficial for many biophysical applications of RM. It has now been established that increased solubilization capacity involves suitable modification of the mechanical properties of the surfactant monolayer and also of the interaction between the RM droplets. Several previous studies have shown that such an improvement could easily be achieved by blending of surfactants. Mixture of surfactants also brings about desired modification in many applications. However, a proper rationale of the process involved is still not vividly understood. In this regard it was pertinent to investigate whether such a modification in the surfactant interface is reflected in the physical properties as well as dynamics of the entrapped water molecules.